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Interlayer Energy Transfer from Naphthalene to Anthracene Chromophores Organized in Langmuir—Blodgett Films
引用本文:LiQianLI ChiMingCHE 等. Interlayer Energy Transfer from Naphthalene to Anthracene Chromophores Organized in Langmuir—Blodgett Films[J]. 中国化学快报, 2002, 13(1): 49-52
作者姓名:LiQianLI ChiMingCHE 等
作者单位:[1]TechnicalInstituteofPhysicsandChemistry,ChineseAcademyofSciences,Beijing100101 [2]DepartmentofChemistry,TheUniversityofHongKong,PokfulamRoad,HongKong
基金项目:国家攀登计划,国家自然科学基金 
摘    要:Interlayer energy transfer between 2,3-naphthol-10-hexadecylaza-15-crown-5(NC16) and N-[1-(9-methoxyanthryl)] decylaza-15-crown-5(A10C) within multilayer Langmuir-Blodgett films has been studied by steady-state fluorescence spectra. The donor and acceptor could be separated precisely by inserting stearic acid (SA) spacers. The efficiency of the energy transfer increases with the decrease in the donor-acceptor distance by a quadratic manner, suggesting the donor excitations are delocalized in the layer.

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Interlayer Energy Transfer from Naphthalene to Anthracene Chromophores Organized in Langmuir-Blodgett Films
Li Qian LI,Li Ping ZHANG,Li Zhu WU,Bo Jie WANG,Chen Ho TUNG,Chi Ming CHE. Interlayer Energy Transfer from Naphthalene to Anthracene Chromophores Organized in Langmuir-Blodgett Films[J]. Chinese Chemical Letters, 2002, 13(1): 49-52
Authors:Li Qian LI  Li Ping ZHANG  Li Zhu WU  Bo Jie WANG  Chen Ho TUNG  Chi Ming CHE
Abstract:Interlayer energy transfer between 2, 3-naphtho-10-hexadecylaza-15-crown-5 (NC16) and N-[1-(9-methoxyanthryl)]decylaza-15-crown-5 (A10C) within multilayer Langmuir-Blodgett films has been studied by steady-state fluorescence spectra. The donor and acceptor could be separated precisely by inserting stearic acid (SA) spacers. The efficiency of the energy transfer increases with the decrease in the donor-acceptor distance by a quadratic manner, suggesting the donor excitations are delocalized in the layer.
Keywords:Energy transfer   L-B film   naphthalene   anthracene.
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