| 弱碱作用下从叔醇简便地合成烯烃 |
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| 引用本文： | 李新生,葛健锋,胡晓春. 弱碱作用下从叔醇简便地合成烯烃[J]. 有机化学, 2005, 25(6): 727-729 |
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| 作者姓名： | 李新生 葛健锋 胡晓春 |
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| 作者单位： | 1. 浙江师范大学化学系,金华,321004
2. 苏州大学材料工程学院,苏州,215006 |
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| 基金项目： | 浙江师范大学校科研和教改项目 |
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| 摘 要： | 用甲磺酸酐和三乙胺作为脱水剂, 发展了一种从叔醇合成烯烃的简便方法, 反应时间短, 温和的条件和高产率使该方法可以快速地从叔醇合成烯烃.
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| 关 键 词： | 叔醇 烯烃 脱水 |
| 收稿时间： | 2004-06-21 |
| 修稿时间： | 2004-06-21 |
Convenient Synthesis of Olefins from Tertiary Alcohols under Mild Basic Condition |
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| LI,Xin-Sheng,GE,Jian-Feng,HU,Xiao-Chun. Convenient Synthesis of Olefins from Tertiary Alcohols under Mild Basic Condition[J]. Chinese Journal of Organic Chemistry, 2005, 25(6): 727-729 |
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| Authors: | LI Xin-Sheng GE Jian-Feng HU Xiao-Chun |
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| Affiliation: | ( Department of Chemistry and Biology, Zhejiang Normal University, Jinhua 321004)( Department of Material and Engineering, Suzhou University, Suzhou 215006) |
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| Abstract: | An efficient method has been achieved for the dehydration of tertiary alcohols using the combi- nation of methanesulfonic anhydride and triethylamine as dehydration agent to obtain olefin in high yield. The short reaction time, mild basic conditions and high yield make it a facile way for the synthesis of olefins from tertiary alcohols. |
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| Keywords: | tertiary alcohol olefin dehydration |
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