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Functional silica nanoparticles synthesized by water-in-oil microemulsion processes
Authors:Tangi Aubert  Fabien Grasset  Stéphane Mornet  Etienne Duguet  Olivier Cador  Stéphane Cordier  Yann Molard  Valérie Demange  Michel Mortier  Hajime Haneda
Institution:1. Université de Rennes 1, UMR, Science Chimiques de Rennes, UR1-CNRS 6226, Equipe Chimie du Solide et Matériaux, Campus de Beaulieu, CS 74205, F-35042 Rennes Cedex, France;2. CNRS, Université de Bordeaux, Institut de Chimie de la Matière Condensée de Bordeaux, 87, Avenue du Docteur Albert Schweitzer, F-33608 PESSAC Cedex, France;3. Ecole Nationale Supérieure de Chimie de Paris, ENSCP, 11 rue P. et M. Curie, Paris F-75005, France;4. National Institute for Materials Science, Namiki 1-1, Tsukuba, Ibaraki 305-0044, Japan
Abstract:Water-in-oil (W/O) microemulsion is a well-suitable confined reacting medium for the synthesis of structured functional nanoparticles of controlled size and shape. During the last decade, it allowed the synthesis of multi-functional silica nanoparticles with morphologies as various as core–shell, homogenous dispersion or both together. The morphology and properties of the different intermediates and final materials obtained through this route are discussed in the light of UV–Vis–NIR spectroscopy, dynamic light scattering (DLS) and X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM) and magnetometer SQUID analysis.
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