| 酸化及碱化膨润土负载镍催化CO2甲烷化反应 |
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| 引用本文： | 张荣斌,徐校燕,王亮,姚刘晶,古宁宇,杨震宇,居艳. 酸化及碱化膨润土负载镍催化CO2甲烷化反应[J]. 应用化学, 2011, 28(2): 203-208. DOI: 10.3724/SP.J.1095.2011.00299 |
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| 作者姓名： | 张荣斌 徐校燕 王亮 姚刘晶 古宁宇 杨震宇 居艳 |
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| 作者单位： | (南昌大学化学系 南昌 330031) |
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| 基金项目： | 国家自然科学基金(20763005); 江西省教育厅基金(GJJ10291)资助项目 |
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| 摘 要： | 采用盐酸和氢氧化钾对膨润土(BEN)进行改性处理,通过浸渍法制备了改性后膨润土负载的镍催化剂,并对其在二氧化碳甲烷化过程中的催化性能进行了研究.借助BET、XRD、TPR和TPD等测试技术对催化剂进行了表征.结果表明,用碱处理后的膨润土比表面积小于酸处理膨润土的,但以碱处理的膨润土为载体所制备的镍催化剂(Ni/alka...
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| 关 键 词： | 改性膨润土 二氧化碳加氢 甲烷化 |
| 收稿时间： | 2010-05-19 |
| 修稿时间： | 2010-07-18 |
Catalytic Methanation of CO2 over Ni Supported on Acidified and Alkalified Bentontie |
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| ZHANG Rongbin,XU Xiaoyan,WANG Liang,YAO Liujing,GU Ningyu,YANG Zhenyu,JU Yan. Catalytic Methanation of CO2 over Ni Supported on Acidified and Alkalified Bentontie[J]. Chinese Journal of Applied Chemistry, 2011, 28(2): 203-208. DOI: 10.3724/SP.J.1095.2011.00299 |
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| Authors: | ZHANG Rongbin XU Xiaoyan WANG Liang YAO Liujing GU Ningyu YANG Zhenyu JU Yan |
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| Affiliation: | (Department of Chemistry,University of Nanchang,Nanchang 330031) |
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| Abstract: | HCl and KOH were used to modify bentonite(BEN).The Ni catalysts supported on acidified and alkalified bentonite had been prepared by aqueous impregnation.Methanation of carbon dioxide was used as a probe reaction to characterize the catalytic performance.The samples were characterized by BET,XRD,TPR and TPD.The results showed that a higher catalyst activity was achieved for Ni/alkali-BEN,although the alkali-BEN had lower surface area.CO2-TPD and H2-TPR study showed that Ni/alkali-BEN could absorb more carbo... |
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| Keywords: | modified-bentonite carbon dioxide hydrogenation methanation |
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