| 莽吉柿中几种双苯吡酮和蒽醌类成分的分离与鉴定 |
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| 引用本文： | 赵岩,刘金平,张连学,蔡恩博,郜玉钢,李平亚. 莽吉柿中几种双苯吡酮和蒽醌类成分的分离与鉴定[J]. 应用化学, 2011, 28(2): 229-233. DOI: 10.3724/SP.J.1095.2011.00159 |
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| 作者姓名： | 赵岩 刘金平 张连学 蔡恩博 郜玉钢 李平亚 |
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| 作者单位： | (1.吉林农业大学中药材学院 长春；2.吉林大学再生医学科学研究所 长春 130021) |
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| 基金项目： | 吉林农业大学中药材学院博士基金(ZYC2009-01)资助项目 |
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| 摘 要： | 对莽吉柿(Pericarpium Garciniae Mangostanae)85%乙醇提取物进一步分离，得到8个双苯吡酮类化合物和1个蒽酮类化合物，经理化性质和NMR及MS谱学数据鉴定分别为α-倒捻子素-3,6-二乙酸酯（α-mangostin-3,6-diyl diacetate，Ⅰ）、1,5,8-三羟基-3-甲氧基-2,4-双-（3-甲基丁-2-烯）双苯吡酮（8-hydroxycudraxanthone G，Ⅱ）、1,3-二羟基-6,7-二甲氧基-2,8-双-（3-甲基丁-2-烯基）双苯吡酮（Cowaxanthone B，Ⅲ）、1,6-二羟基-3,5-二甲氧基-2-（3-甲基丁-2-烯基）双苯吡酮（Cowaxanthone A，Ⅳ）、1,5-二羟基-4-（3-甲基丁-2-烯基）-6′,6′-二甲基吡喃[2′,3′:3,2]双苯吡酮（trapezifolixanthone，Ⅴ）、1,6-二羟基-6′,6′-二甲基吡喃[2′,3′:7,8]-6″,6″-二甲基吡喃[2″,3″:3,2-]双苯吡酮（brasilixanthone B，Ⅵ）、1,3,5-三羟基-2-（3-甲基丁-2-烯）-4-（1,1-二甲基-2-烯丙基）双苯吡酮（Allanxanthone A，Ⅶ）、1,3,8-三羟基-5-甲氧基-2,4-双-（3-甲基丁-2-烯）双苯吡酮(2,4-di-(3-methylbut-2-enyl)-1,3,8-trihydroxy-5-methoxyxanthone,Ⅷ)、1,4,8-三羟基-6-甲基-3-甲氧基-9,10-蒽酮(1,4,8-trihydroxy-6-methyl-3-methoxy- 9,10-anthraquinone, Ⅸ）。 其中化合物Ⅰ、Ⅴ、Ⅵ、Ⅶ、Ⅸ为首次从藤黄属植物中分离得到，化合物Ⅱ、Ⅲ、Ⅳ、Ⅷ为首次从该植物中分离得到。
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| 关 键 词： | 山竹 双苯吡酮 蒽醌 分离 鉴定 |
| 收稿时间： | 2010-03-18 |
| 修稿时间： | 2010-06-25 |
Isolation and Identification of Several Xanthones and Anthraquinone from Pericarpium Garciniae Mangostanae |
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| ZHAO Yan,LIU Jinping,ZHANG Lianxue,CAI Enbo,GAO Yugang,LI Pingya. Isolation and Identification of Several Xanthones and Anthraquinone from Pericarpium Garciniae Mangostanae[J]. Chinese Journal of Applied Chemistry, 2011, 28(2): 229-233. DOI: 10.3724/SP.J.1095.2011.00159 |
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| Authors: | ZHAO Yan LIU Jinping ZHANG Lianxue CAI Enbo GAO Yugang LI Pingya |
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| Affiliation: | ( 1.College of Chinese Medicine Materials,Jilin Agricultural University,Changchun;2.Institute of Frontier Medical Science of Jilin University,Changchun 130021) |
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| Abstract: | Eight xanthones and one anthraquinone were isolated by chromatographic separation of 85% ethanol extract of Pericarpium Garciniae Mangostanae. The obtained compounds were identified as α-mangostin-3,6-diyl diacetate(Ⅰ), 8-hydroxycudraxanthone G(Ⅱ), cowaxanthone B(Ⅲ), cowaxanthone A(Ⅳ), trapezifolixanthone(Ⅴ), brasilixanthone B(Ⅵ), allanxanthone A(Ⅶ), 2,4-di-(3-methylbut-2-enyl)-1,3,8-trihydroxy-5-methoxyxanthone(Ⅷ), and 1,4,8-trihydroxy-6-methyl-3-methoxy-9,10-anthraquinone(Ⅸ) by physico-chemical properties, NMR and MS spectral data, compounds Ⅰ, Ⅴ, Ⅵ, Ⅶ and Ⅸ were isolated from plants of Garcinia for the first time, and compounds Ⅱ, Ⅲ, Ⅳ and Ⅷ were isolated from Pericarpium Garciniae Mangostanae for the first time. |
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| Keywords: | Garcinia mangostana xanthone anthraquinone isolation identification |
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