Isomeric composition of ditolyls formed upon the thermal decomposition of an anionic Pt(IV) σ-tolyl chloride complex |
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| Authors: | G B Shul'pin A E Shilov G V Nizova A K Yatsimirskii S A Deiko P Lederer |
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| Institution: | (1) Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow;(2) M. V. Lomonosov Moscow State University, USSR;(3) A. N. Bakh Institute of Biochemistry, Academy of Sciences of the USSR, Moscow;(4) Institute of Inorganic Chemistry, Czechoslovak Academy of Sciences, Prague, Czechoslovakia |
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| Abstract: | Conclusion Heating a solution of PtCl6
2– ions and toluene in CF3CO2H-H2O leads to the formation of a platinum(IV)  -tolyl complex which decomposes in the presence of free toluene to give 3,3 -, 4,4-, 3,4-, 2,3- and 2,4-ditolyls.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2377–2380, October, 1986.This study was carried out in the framework of the Cooperation Program of Catalysis Scientists at the academies of sciences of the Socialist countries. |
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