CRYSTAL AND MOLRCULAR STRUCTURE OF-N-METHYLPHENOTHIAZINE RADICAL CATION HEXACHLOHOANTIMONATK,MPT SbCl6- |
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摘 要: | <正> C13H11NSSbCl6,Mr = 547.8, Monoclinic,C2, a = 11.045(2), b 11.466(3), c = 8.606(2)A,β=121.4(2)°,V=930.2A3,Z = 2.MoKα,λ 0.711 A. Room temperature, final R=0.038 for 1389 unique reflections wit I> 3.00(I).Pronounced deformation of the molecular structure has been ob served when the neutral N-methylphenothiazine is transformed into its radi cal cation MPT+.
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CRYSTAL AND MOLRCULAR STRUCTURE OF-N-METHYLPHENOTHIAZINE RADICAL CATION HEXACHLOHOANTIMONATK,MPT SbCl6- |
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Abstract: | C13H11NSSbCl6,Mr = 547.8, Monoclinic,C2, a = 11.045(2), b 11.466(3), c = 8.606(2)A,β=121.4(2)°,V=930.2A3,Z = 2.MoKα,λ 0.711 A. Room temperature, final R=0.038 for 1389 unique reflections wit I> 3.00(I).Pronounced deformation of the molecular structure has been ob served when the neutral N-methylphenothiazine is transformed into its radi cal cation MPT+. |
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