Oxidation-reduction Conversions of 1,4-Dihydropyridine Derivatives on Interaction of Alicyclic 1,5-Diketones with Nitroanilines |
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Authors: | K V Maslov A G Egorov T I Akimova V A Kaminski |
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Institution: | (1) Far Eastern State University, Vladivostok, 690600, Russia |
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Abstract: | On interaction of alicyclic 1,5-diketones and the products of their intramolecular aldol condensation with 2- and 4-nitroanilines and 2,4-dinitroaniline reduction occurs of the nitro group by the intermediately formed 1,4-dihydropyridine derivatives. The reaction products are N-nitrophenyl- and N-aminophenylpyridinium salts and also N,N-phenylenebispyridinium salts. |
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Keywords: | alicyclic 1 5-diketones 2 4-dinitroaniline 2-nitroaniline 4-nitroaniline pyridinium salts reduction |
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