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Oxidation-reduction Conversions of 1,4-Dihydropyridine Derivatives on Interaction of Alicyclic 1,5-Diketones with Nitroanilines
Authors:K V Maslov  A G Egorov  T I Akimova  V A Kaminski
Institution:(1) Far Eastern State University, Vladivostok, 690600, Russia
Abstract:On interaction of alicyclic 1,5-diketones and the products of their intramolecular aldol condensation with 2- and 4-nitroanilines and 2,4-dinitroaniline reduction occurs of the nitro group by the intermediately formed 1,4-dihydropyridine derivatives. The reaction products are N-nitrophenyl- and N-aminophenylpyridinium salts and also N,N-phenylenebispyridinium salts.
Keywords:alicyclic 1  5-diketones  2  4-dinitroaniline  2-nitroaniline  4-nitroaniline  pyridinium salts  reduction
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