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Drastic difference in the photo-driven hydrogenation reactions of ruthenium complexes containing NAD model ligands
Authors:Ohtsu Hideki  Tanaka Koji
Institution:Institute for Molecular Science, 5-1 Higashiyama, Myodaiji, Okazaki, Aichi 444-8787, Japan.
Abstract:Successful control of photo-driven NAD(+)/NADH type hydrogenation reactions in ruthenium complexes has been accomplished by using a new NAD(+) model ligand with modulated distortion of the ligand taking advantage of the substituent effect.
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