溶胶-凝胶法制备ZnO薄膜的成核-生长和失稳分解研究

采用溶胶-凝胶法在ZnWO₄单晶上制备出透明的ZnO薄膜.通过光学显微镜观察了Z nO薄膜的表面形貌.实验结果表明，ZnO薄膜的形成经历了表面成核，晶粒长大和岛的形成三 个不同的阶段.由于ZnO晶核是在非平衡条件下生长的，在生长过程中不可避免地出现了枝晶 生长和分形生长以及失稳分解. 关键词： 氧化锌薄膜 成核 枝晶生长 分形生长 失稳分解

Nucleation-growth and spinodal decomposition of zinc oxide films prepared by sol-gel technique

Transparent zinc oxide (ZnO) films were prepared on ZnWO₄ crystal by sol-gel technique. Surface morphology of ZnO films were observed with optical mi croscope. The results of show that ZnO films are formed in three different stage s from nucleation on surface, grain growth to island formation. Because ZnO crys tal nucleus were grown under non_equilibrium condition, it is inevitable that de ndrite growth, fractal growth and spinodal decomposition phenomenon are involved in the growing process.