Synthesis and Structure of (Oxydiacetato)-nickel(II) Complex with Diaminobithiazole |
| |
| Institution: | Department of Chemistry, Zhejiang University, Hangzhou 310012, China;Key Laboratory of Fine Chemical Engineering, Jiangsu Polytechnic University, Changzhou 213016, China;Department of Chemistry, Zhejiang University, Hangzhou 310012, China;Key Laboratory of Fine Chemical Engineering, Jiangsu Polytechnic University, Changzhou 213016, China;Department of Chemistry, Zhejiang University, Hangzhou 310012, China;Key Laboratory of Fine Chemical Engineering, Jiangsu Polytechnic University, Changzhou 213016, China |
| |
| Abstract: | The title complex Ni(C4H4O5)(C6H6N4S2)(H2O)]2.5H2O has been prepared and its crystal structure was determined by X-ray diffraction method. The crystal belongs to monoclinic, space group P21/n with a = 16.499(2), b = 10.132(1), c = 11.177(2) , b = 109.76(1)o, V = 1758.4(4) 3, Mr = 452.11, Z = 4, Dc = 1.708 g/cm3, m = 1.391 mm-1, F(000) = 932, R = 0.0424 and wR = 0.1088 for 2341 observed reflec- tions (I>2s(I)). The complex assumes a distorted octahedral coordination geometry formed by one oxydiacetate dianion, one diaminobithiazole and one coordinated water molecule. The parallel thiazole rings of adjacent complex molecules overlap to each other, and the separation of 3.458(7) ?suggests the existence of - stacking. |
| |
| Keywords: | Ni(II) complex oxydiacetate crystal structure synthesis diaminobithiazole |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
