Synthesis and structures of tris(pentafluorophenyl)silylamines |
| |
| Authors: | V V Levin A D Dilman A A Korlyukov P A Belyakov M I Struchkova M Yu Antipin V A Tartakovsky |
| |
| Institution: | (1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation;(2) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991 Moscow, Russian Federation |
| |
| Abstract: | Tris(pentafluorophenyl)silylamines were synthesized by silylation of amines and imines with (C6F5)3SiCl or (C6F5)3SiOTf in the presence of triethylamine. The crystal structures of the (C6F5)3SiN(H)CH2Ph and (C6F5)3SiN(CH=CMe2)CH2Ph compounds were studied by X-ray diffraction. The crystal packings were analyzed by quantum chemical calculations in terms
of the density functional theory (PBE exchange-correlation functional).
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1345–1352, July, 2007. |
| |
| Keywords: | amines imines silylation organosilicon compounds organofluorine compounds X-ray diffraction analysis quantum chemical calculations |
| 本文献已被 SpringerLink 等数据库收录！ |
|
