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A simplified hard-sphere equation of state meeting the high and low density limits
Authors:Mohammad K. Khoshkbarchi  Juan H. Vera
Affiliation:

Department of Chemical Engineering, McGill University, Montreal, P.Q., H3A 2A7, Canada

Abstract:A simplified hard-sphere equation of state has been developed, which meets the correct limit for close-packed conditions. It is shown that the proposed equation of state for hard spheres can represent accurately the computer simulation compressibility factor data and virial coefficients over a wide density range. The comparison of the results of the calculations using this equation, the Carnahan-Starling equation, and the two equations proposed by Iglesias-Silva and Hall, shows that the equation proposed here represents the compressibility factor data and the virial coefficients with better accuracy.
Keywords:Hard sphere   Equation of state
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