Solvent effects on intermolecular proton transfer: the rates of nitrene protonation and their correlation with Swain acity |
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| Authors: | Wang Jin Burdzinski Gotard Platz Matthew S |
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| Affiliation: | Department of Chemistry, The Ohio State University, 100 West 18th Avenue, Columbus, Ohio 43210, USA. |
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| Abstract: | The rate of protonation of singlet 2-fluorenylnitrene was studied in eight protic solvents. The protonation rates vary between 10(11) and 10(9) s(-1) and are well-correlated with Swain's acity parameters. This demonstrates that Swain acity parameters and nitrene protonation rates can be used to evaluate bulk solvent acidity. |
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