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Direct nucleophilic fluorination of carbonyl groups of benzophenones and benzils with Deoxofluor
Authors:Ying Chang
Institution:Department of Chemistry, University of Nevada Las Vegas, 4505 Maryland Parkway, Box 454003, Las Vegas, NV 89154-4003, United States
Abstract:The carbonyl groups of diaryl ketones and diaryl diketones were directly fluorinated with bis(2-methoxyethyl)aminosulfur trifluoride (Deoxofluor) under neat conditions to give the corresponding gem-difluorides and tetrafluorinated derivatives in moderate to high yields.
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