Using stereoelectronic effects to explain selective reactions of 4-substituted five-membered ring oxocarbenium ions |
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Authors: | Smith Deborah M Woerpel K A |
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Institution: | Department of Chemistry, University of California-Irvine, Irvine, California 92697-2025, USA. |
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Abstract: | reaction: see text] The utility of the inside attack model to predict and analyze the stereoselectivities of nucleophilic additions to complex five-membered ring oxocarbenium ions is demonstrated in a systematic study of C-4-substituted acetals. |
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