On the pattern of hydrogenolysis of hexane isomers over four Group VIIIB metals |
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Authors: | Z Paál and P Tétényi |
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Institution: | (1) Institute of Isotopes of the Hungarian Academy of Sciences, P.O. Box 77, H-1525 Budapest, Hungary |
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Abstract: | The hydrogenolysis patterns of five hexane isomers have been compared over Rh, Pd, Ir and Pt. The selectivity of rupture of various C–C bond types is different for various metals. The fingerprint-like patterns are, as a rule, similar to those reported in the literature, their correlation with the position of the metal in the periodic system is pointed out.
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