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Reactions of carbanions of bis(dialkoxyphosphoryl)bromomethane with fullerenes C60 and C70
Authors:Nuretdinov  I A  Gubskaya  V P  Shishikina  N I  Fazleeva  G M  Berezhnaya  L Sh  Karaseva  I P  Sibgatullina  F G  Zverev  V V
Institution:(1) Kazan Research Center of the Russian Academy of Sciences, A. E. Arbuzov Institute of Organic and Physical Chemistry, 8 ul. Akad. Arbuzova, 420088 Kazan, Russian Federation
Abstract:The reactions of carbanions of bis(dialkoxyphosphoryl)bromomethanes with fullerenes C60 and C70 afforded new bis(dialkoxyphosphoryl)methanofullerenes C60 and C70, respectively, whose structures were established by spectroscopic methods.
Keywords:bis(dialkoxyphosphoryl)bromomethanes  fullerenes C60 and C70  methanofullerenes  UV and IR spectra  1H  13C  and 31P NMR spectra  the Bingel reaction  quantum-chemical calculations  PM3 method
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