Rigid triol and diol with adamantane‐like core derived from naturally occurring myo‐inositol and their polyaddition with diisocyanates |
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Authors: | Shusuke Okamoto Shohei Onoue Masakazu Kobayashi Atsushi Sudo |
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Affiliation: | Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University, , Higashi Osaka, Osaka, 577‐8502 Japan |
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Abstract: | Two orthoester derivatives 1 and 2 that are easily accessible from naturally occurring myo‐inositol were exploited as new triol‐ and diol‐type monomers bearing a rigid adamantane‐like structure to polyaddition with diisocyanates that gave the corresponding networked and linear polyurethanes. DSC analysis of the networked polyurethanes revealed their high glass transition temperatures ranging from 155 to 248 °C, suggesting the contribution of the rigidity of the adamantane‐like structure introduced at the nodes of the networked polyurethanes 6. Besides, the polyaddition of 2 with diisocyanates gave the corresponding linear polyurethanes 4, of which glass transition temperatures were high, ranging from 105 to 177 °C, presumably by virtue of the rigidity of the adamantane‐like structure introduced into the main chains. Tgs of the networked polyurethanes 6 were higher than those of the linear polyurethanes 4. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 3498–3505 |
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Keywords: | high performance polymers linear networks polyurethanes renewable resources thermal properties |
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