Liquid Crystalline Dispersions of Graphene‐Oxide‐Based Hybrids: A Practical Approach towards the Next Generation of 3D Isotropic Architectures for Energy Storage Applications |
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| Authors: | Alfred T Chidembo Seyed H Aboutalebi Konstantin Konstantinov David Wexler Hua K Liu Shi X Dou |
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| Institution: | 1. Institute for Superconducting and Electronic Materials, AIIM Facility, Innovation Campus, University of Wollongong, , North Wollongong, NSW, 2522 Australia;2. School of Materials, Mechanical and Mechatronics Engineering, University of Wollongong, , Wollongong, NSW, 2519 Australia |
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| Abstract: | We report the use of the spray pyrolysis method to design self‐assembled isotropic ternary architectures made up of reduced graphene oxide (GO), functionalized multiwalled carbon nanotubes, and nickel oxide nanoparticles for cost‐effective high‐performance supercapacitor devices. Electrodes fabricated from this novel ternary system exhibit exceptionally high capacitance (2074 Fg?1) due to the highly conductive network, synergistic link between GO and carbon nanotubes and achieving high surface area monodispersed NiO decorated rGO/CNTs composite employing the liquid crystallinity of GO dispersions. To further assess the practicality of this material for supercapacitor manufacture, we assembled an asymmetric supercapacitor device incorporating activated carbon as the anode. The asymmetric supercapacitor device showed remarkable capacity retention (>96%), high energy density (23 Wh kg?1), and a coulombic efficiency of 99.5%. |
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| Keywords: | graphene oxide spray pyrolysis pseudocapacitance liquid crystal |
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