Interaction between particles in solution and the mechanism of dihydrogen activation in base catalyzed isotope exchange reactions |
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Authors: | A A Medvinskii Yu M Baikov and N N Bulgakov |
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Institution: | (1) Polytechnical Institute, Tomsk, USSR;(2) Physico-Technical Institute, Leningrad, USSR;(3) Institute of Catalysis, Novosibirsk, USSR |
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Abstract: | A previously suggested mechanism for the H-D isotope exchange of dihydrogen with aqueous alkaline and amide-ammonia solutions is discussed to be generalized and extended to hydrogen isotope exhange with other protolytic solvents.
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