Physicochemical study of new polydentane ligand systems based on 2,6-diformyl-4-<Emphasis Type="Italic">tert</Emphasis>-butylphenol |
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| Authors: | Yu P Tupolova I N Shcherbakov L D Popov S I Levchenkov O I Askalepova A V Mishchenko V V Lukov V A Kogan |
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| Institution: | 1.Southern Federal University,Rostov-on-Don,Russia;2.Southern Scientific Center of Russian Academy of Sciences,Rostov-on-Don,Russia |
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| Abstract: | New polydentate ligand systems, products of condensation of 2,6-diformyl-4-tert-butylphenol with 1,3-diaminopropanol-2 and carbo(thiocarbo)hydrazide, were synthesized and their structure was determined
based on the data of elemental analysis, 1H NMR and IR spectroscopy. The acid-base properties of bisazomethine I have been studied. Spatial structure and spectral properties of the ligand system were simulated using quantum-chemical calculations. |
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