Photo-induced hydrogen production in a helical peptide incorporating a [FeFe] hydrogenase active site mimic |
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| Authors: | Anindya Roy Christopher Madden Giovanna Ghirlanda |
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| Institution: | Center for Bio-inspired Solar Fuel Production, Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287-1604, USA. gghirlanda@asu.edu. |
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| Abstract: | There is growing interest in the development of hydrogenase mimics for solar fuel production. Here, we present a bioinspired mimic designed by anchoring a diiron hexacarbonyl cluster to a model helical peptide via an artificial dithiol amino acid. The FeFe]-peptide complex catalyses photo-induced production of hydrogen in water. |
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