Use of a recyclable poly(N-vinyl carbazole) palladium(II) complex catalyst: Heck cross-coupling reaction under phosphine-free and aerobic conditions |
| |
| Authors: | Manirul Islam Paramita Mondal Anupam Singha Roy Kazi Tuhina |
| |
| Affiliation: | (1) Department of Chemistry, University of Kalyani, Kalyani, Nadia, 741235, WB, India;(2) Department of Chemistry, B.S. College, S-24 P.G.S., Canning, 743329, WB, India |
| |
| Abstract: | A poly(3,6-dibenzaldimino N-vinyl carbazole) Pd(II) complex has been synthesized and characterized by physicochemical and spectroscopic techniques. The complex was found to be highly active toward hydrogenation reactions of various organic substrates under atmospheric pressure at ambient temperature. A tentative reaction mechanism is proposed on the basis of kinetic studies and isolation of reactive intermediates. The catalyst shows good conversion rates, thermal stability and recyclability. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
