Kinetics of p-xylene oxidation catalyzed by cobalt oxide |
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| Authors: | M Hronec and J Ilavský |
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| Institution: | (1) Depatment of Organic Technology, Faculty of Chemistry, Slovak Technical University, 812 37 Bratislava, Czechoslovakia |
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| Abstract: | Kinetics of p-xylene oxidation in an aqueous system catalyzed by cobalt oxide have been studied at 140 °C under oxygen. The reaction is second order in p-xylene and first order in cobalt oxide concentration. The rate constant and product distribution are very close to those found for homogeneous catalytic reactions. Based on these findings, a reaction scheme describing the influence of oxide catalyst is formulated.              -    ,   , 140° C   .    -  .    ,  .   ,   . |
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