|
|||||
|
|
Catalytic dechlorination of aromatic chlorides with Pd/C catalyst in alkaline 2-propanol: activity enhancement by the addition of methanol |
|
| Authors: | Yuji Ukisu and Tatsuo Miyadera |
| Institution: | (1) National Institute of Advanced Industrial Science and Technology (AIST), AIST Tsukuba West, 16-1 Onogawa, Tsukuba, Ibaraki 305-8569, Japan;(2) National Institute of Advanced Industrial Science and Technology (AIST), AIST Tsukuba West, 16-1 Onogawa, Tsukuba, Ibaraki 305-8569, Japan |
| Abstract: | Summary p- and o-Chloroanisole were catalytically dechlorinated with Pd/C at 30°C in a solution of NaOH in mixtures of 2-propanol and methanol. The dechlorination rate of p-chloroanisole in the mixture containing 1% methanol was 12 times as high as that in 2-propanol alone. The dechlorination rate of o-chloroanisole was also enhanced by the addition of a small amount of methanol. |
| Keywords: | supported palladium catalyst liquid phase Dechlorination rate chloroanisole |
| 本文献已被 SpringerLink 等数据库收录！ | |