Synthesis and characterization of functionalized ferrocenylsilanes bearing a bulky substituent |
| |
| Authors: | Takahiro Sasamori Megumi Kobayashi Noriyoshi Nagahora Yusuke Sugiyama Norihiro Tokitoh |
| |
| Institution: | (1) Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan |
| |
| Abstract: | Several types of overcrowded ferrocenylsilanes, Tbt(Fc)SiX2(Tbt=2, 4, 6-trisbis(trimethylsilyl)methyl]phenyl, Fc=ferrocenyl, X = H, OH, and Br) were synthesized and characterized. In addition, DFT calculations for ferrocenylsilanediol systems indicated
the existence of the intramolecular hydrogen bonding between the Fe atom and H–O moiety in Tbt(Fc)Si(OH)2.
Dedicated to Professor Mitsuo Kira on the occasion of his 2005 Wacker Awardy |
| |
| Keywords: | silicon steric protection ferrocene cyclic voltammetry hydrogen bond |
| 本文献已被 SpringerLink 等数据库收录！ |
|
