Increasing the crystallisation temperature to access new spin clusters: conversion of [Ni8(cit)6(OH)2(H2O)2]10- to [Ni8(cit)6(OH)2]10- |
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| Authors: | Murrie Mark Biner Daniel Stoeckli-Evans Helen Güdel Hans U |
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| Institution: | Departement für Chemie und Biochemie, Universit?t Bern, Freiestrasse 3, 3000 Bern 9, Switzerland. mark.murrie@iac.unibe.ch |
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| Abstract: | The role of temperature in the formation of high nuclearity nickel(II) citrate spin clusters is explored, revealing how changes in structure and hence magnetic properties can be triggered through desolvation and ligand reorganisation. |
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