Heat inhibited reactions |
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| Authors: | Davies D Martin Stringer Estelle L |
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| Affiliation: | Division of Chemical Sciences, School of Applied Sciences, Northumbria University, Newcastle upon Tyne, UK NET 8ST. martin.davies@unn.ac.uk |
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| Abstract: | Acyl transfer from p-nitrophenyl trimethylacetate to hydrogen peroxide in millimolar aqueous solutions of an amphiphilic poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) triblock copolymer slows down as the temperature is raised due to partitioning of the hydrophobic ester into heat-induced micelles. |
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