An anionic organic mixed-valence system with a remarkably well-resolved vibrational structure in its intervalence band |
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Authors: | Risko Chad Barlow Stephen Coropceanu Veaceslav Halik Marcus Brédas Jean-Luc Marder Seth R |
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Institution: | Department of Chemistry, The University of Arizona, Tucson, Arizona 85721-0041, USA. |
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Abstract: | The reduction of a phenylene-bridged bis(dioxaborine) affords a strongly delocalised organic mixed-valence system; for the first time details of the vibrations coupled to the electron transfer have been extracted from the intervalence band. |
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