| 3,6-二氨基-N-异丁基邻苯二甲酰亚胺的合成 |
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| 引用本文： | 陈碧琼,杨心师,袁立华,冯文.3,6-二氨基-N-异丁基邻苯二甲酰亚胺的合成[J].合成化学,2011,19(6):744-746. |
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| 作者姓名： | 陈碧琼 杨心师 袁立华 冯文 |
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| 作者单位： | 四川大学化学学院教育部辐射物理与技术重点实验室原子核科学技术研究所,四川成都,610064 |
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| 摘 要： | 以3-硝基邻苯二甲酸为原料,经脱水成酐、氨解、还原酰化、硝化、水解、还原等六步反应合成了一种新型的环芳酰胺的构筑单元对苯二胺衍生物——3,6-二氨基-N-异丁基邻苯二甲酰亚胺,总收率16.4％,其结构经1H NMR,13C NMR和ESI-MS表征.
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| 关 键 词： | 3 6-二氨基-N-异丁基邻苯二甲酰亚胺 3-硝基邻苯二甲酸 对苯二胺衍生物 合成 |
Synthesis of 3,6-Diamino-N-isobutyl Phthalimide |
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| CHEN Bi-qiong,YANG Xin-si,YUAN Li-hua,FENG Wen.Synthesis of 3,6-Diamino-N-isobutyl Phthalimide[J].Chinese Journal of Synthetic Chemistry,2011,19(6):744-746. |
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| Authors: | CHEN Bi-qiong YANG Xin-si YUAN Li-hua FENG Wen |
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| Institution: | CHEN Bi-qiong,YANG Xin-si,YUAN Li-hua,FENG Wen(Key Laboratory for Radiation Physics and Technology of Ministry of Education,College of Chemistry,Institute of Nuclear Science and Technology,Sichuan University,Chengdu 610064,China) |
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| Abstract: | A novel derivative of phenylene diamine,3,6-diamino-N-isobutyl phthalimide,was designed and synthesized by a six-step reaction of dehydration,ammonolysis,reduction and acylation,nitration,hydrolysis and hydrogenation from 3-nitrophthalic acid.The total yield was 16.4% and the structures were characterized by 1H NMR,13C NMR and ESI-MS. |
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| Keywords: | 3 6-diamino-N-isobutylphthalimide 3-nitrophthalic acid p-phenylene diamine derivative synthesis |
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