| 水相中磷钼酸催化三组分合成烯丙基胺 |
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| 引用本文： | 解正峰a,c 李桂龙b 赵刚b 王吉德a,c. 水相中磷钼酸催化三组分合成烯丙基胺[J]. 中国化学, 2009, 27(5): 925-929. DOI: 10.1002/cjoc.200990157 |
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| 作者姓名： | 解正峰a c 李桂龙b 赵刚b 王吉德a c |
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| 作者单位： | a新疆大学石油天然气精细化工教育部重点实验室 乌鲁木齐 830046 ;b中国科学院上海有机化学研究所现代有机合成实验室 上海 200032 ;c西安交通大学理学院 西安 310012 ; |
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| 摘 要： | 以磷钼酸作为催化剂，芳香醛、胺和三丁基烯丙基锡三组分在水作为溶剂，室温下高产率的得到相应的烯丙基胺。
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| 关 键 词： | allylation phosphomolybdic acid allyltributylstannane homoallylic amine water |
| 收稿时间： | 2008-05-15 |
| 修稿时间： | 2008-10-10 |
Three‐component Synthesis of Homoallylic Amines Catalyzed by Phosphomolybdic Acid in Water |
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| Zhengfeng XIE,Guilong LI,Gang ZHAO,Jide WANG. Three‐component Synthesis of Homoallylic Amines Catalyzed by Phosphomolybdic Acid in Water[J]. Chinese Journal of Chemistry, 2009, 27(5): 925-929. DOI: 10.1002/cjoc.200990157 |
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| Authors: | Zhengfeng XIE Guilong LI Gang ZHAO Jide WANG |
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| Affiliation: | 1. Kay Laboratory of Oil & Fine Chemicals of Ministry of Education, Xinjiang University, Urumqi, Xinjiang 830046, China;2. School of Sciences, Xi'an Jiaotong University, Xi'an, Shaanxi 710049, China;3. Fax: 0086‐991‐8582807;4. 0086‐21‐64166128 |
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| Abstract: | The three‐component reactions of aromatic aldehydes, amines and allyltributylstannane in water catalyzed by phosphomolybdic acid (PMA), underwent smoothly to afford the corresponding homoallylic amines in high yields at room temperature. |
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| Keywords: | allylation phosphomolybdic acid allyltributylstannane homoallylic amine water |
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