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Influence of the substituent on selective photocatalytic oxidation of aromatic compounds in aqueous TiO2 suspensions
Authors:Palmisano Giovanni  Addamo Maurizio  Augugliaro Vincenzo  Caronna Tullio  García-López Elisa  Loddo Vittorio  Palmisano Leonardo
Institution:Dipartimento di Ingegneria Chimica dei Processi e dei Materiali, Università degli Studi di Palermo, Viale delle Scienze, 90128 Palermo, Italy. giovanni_palmisano@yahoo.it
Abstract:Experimental results are reported showing that the photocatalytic oxidation of aromatic compounds containing an electron-donor group (EDG) gives rise mainly to ortho- and para-monohydroxy derivatives while in the presence of an electron-withdrawing group (EWG) all the monohydroxy derivatives are obtained.
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