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Tetramethylsilane as reagent gas: mass spectra of nitrocarboxylic acid esters and nitroalcohols |
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| Authors: | V. I. Kadentsev N. G. Kolotyrkina A. A. Stomakhin O S. Chizhov S. L. Ioffe I. M. Lypkalo A. D. Dil'man A. A. Tishkov |
| Affiliation: | (1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913 Moscow, Russian Federation |
| Abstract: | Nitrocarboxylic acid esters and nitroalcohols react with trimethylsilyl cation in the gas phase under conditions of chemical ionization to form stable [M+SiMe3]+ ions. The pathways of their fragmentation were established and characteristic distinctions in the mass spectra caused by mutual arrangement of functional groups were found. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1257–1259, June, 1998. |
| Keywords: | mass-spectrometry chemical ionization trimethylsilyl cation nitrocarboxylic acid esters nitroalcohols |
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