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The millimeter-wave spectrum of chlorine nitrate (ClONO2): The ν6 vibrational state |
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| Authors: | Rebecca AH Butler Paul Helminger Ewa Bialkowska-Jaworska |
| Institution: | a Department of Physics, Pittsburg State University, Pittsburg, KS 66762, USA b Department of Physics, Wright State University, Dayton, OH 45435, USA c Department of Physics, University of South Alabama, Mobile, AL 36688, USA d Department of Physics, The Ohio State University, 191 W. Woodruff Avenue, Columbus, OH 43210, USA e Institute of Physics, Polish Academy of Sciences, Al. Lotników 32/46, 02-668 Warszawa, Poland |
| Abstract: | The pure rotational spectrum of chlorine nitrate in its v6 = 1 excited vibrational state has been studied. A total of 2901 lines, with Ka extending to 33 in the 35Cl isotopologue and 30 in the 37Cl isotopologue, respectively, have been recorded and assigned. This analysis, along with our recently reported study of the ν5/ν6ν9 dyad and the improved energy levels of ν9 reported in this paper, should make possible accurate simulation of the corresponding ν6 band and its complex hot band structure near 435 cm−1. |
| Keywords: | Chlorine nitrate ClONO2 Millimeter Spectra Spectroscopy Remote sensing Atmosphere |
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