Synthetic studies on maitotoxin. 1. Stereoselective synthesis of the C'D'E'F'-ring system having a side chain |
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| Authors: | Morita Masayuki Ishiyama Seishi Koshino Hiroyuki Nakata Tadashi |
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| Institution: | RIKEN, The Institute of Physical and Chemical Research, Saitama, Japan. |
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| Abstract: | The stereoselective synthesis of the maitotoxin C'D'E'F'-ring system having a side chain has been accomplished through a convergent strategy. The key reactions include Horner-Wadsworth-Emmons coupling of the C'D'E'-ring and the side chain and subsequent construction of the F'-ring by silane reduction of dihydropyran. |
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