|
|||||
|
|
S-Methylation of polythiolactam: chemical transformation of macrocyclic anion receptor into new macrocyclic ligand for metal ions |
|
| Authors: | Junichi Sawada Takakazu Yamamoto |
| Affiliation: | a Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan b Tsukuba Research Center for Interdisciplinary Materials Science (TIMS), University of Tsukuba, 1-1-1 Tennoudai, Tsukuba 305-8573, Japan c Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennoudai, Tsukuba 305-8573, Japan |
| Abstract: | The S-methylation of a macrocyclic tetrathiolactam afforded a new macrocyclic thioimidate that exhibited good affinity toward metal ions. The molecular structures of the macrocyclic ligand and its metal complexes were determined by X-ray crystallography. |
| Keywords: | Macrocycle Thioamide Thioimidate Metal complexes |
| 本文献已被 ScienceDirect 等数据库收录！ | |