Synthetic studies of new CMP-sialic acid analogues applying a novel buffer-mediated rearrangement |
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| Authors: | Satomi Niwayama Venkata Subbarao Kandula Xiao Chen |
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| Institution: | a Department of Chemistry and Biochemistry, Texas Tech University, Lubbock, TX 79409-1061, USA
b Department of Chemistry, Oklahoma State University, Stillwater, OK 74078-3071, USA |
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| Abstract: | Synthetic studies of analogues of cytidine monophosphate (CMP)-sialic acid as transition state mimics for sialylation are reported, applying selective monohydrolysis of a symmetric diester and a subsequent buffer-mediated regio- and stereospecific rearrangement we reported earlier. |
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