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trans-α-Necrodyl isobutyrate, the sex pheromone of the grape mealybug, Pseudococcus maritimus
Authors:Bruno A. Figadè  re,J. Steven McElfresh,Kent M. Daane,Jocelyn G. Millar
Affiliation:a Department of Entomology, University of California, Riverside, CA 92521, USA
b UMR CNRS 8076, University Paris-Sud, Laboratoire de Pharmacognosie, UFR de Pharmacie, Chaˆtenay-Malabry F-92296, France
c Department of Chemistry, University of California, Riverside, CA 92521, USA
d Department of Environmental Science, Policy, and Management, University of California, Berkeley, CA 94720, USA
e Kearney Agricultural Center, University of California, Parlier, CA 93648, USA
Abstract:Headspace volatiles of virgin female grape mealybugs contained a single compound that elicitited responses from antennae of males in GC-electroantennogram analyses. The structure, identified as (R,R)-trans-(3,4,5,5-tetramethylcyclopent-2-en-1-yl)methyl 2-methylpropanoate, an irregular, non-head-to-tail monoterpenoid, was confirmed by synthesis.
Keywords:(R&lowast  ,R&lowast  )-trans-(3,4,5,5-Tetramethylcyclopent-2-en-1-yl)methyl 2-methylpropanoate   Pheromone   Irregular terpenoid   Necrodol
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