Highly selective methanesulfonic acid-catalyzed 1,3-isomerization of allylic alcohols |
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| Authors: | Rajender Reddy Leleti Bin Hu Mahavir Prashad Oljan Repi? |
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| Institution: | Process R&D, Chemical and Analytical Development, Novartis Pharmaceuticals Corporation, One Health Plaza, East Hanover, NJ 07936, USA |
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| Abstract: | Secondary and tertiary allylic alcohols undergo 1,3-isomerization smoothly in the presence of methanesulfonic acid under simple and efficient conditions to afford selectively the corresponding primary E-allylic alcohols in excellent yields. |
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| Keywords: | Methanesulfonic acid Allylic alcohols 1 3-Isomerization THF Water |
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