Novel quinone-fused corroles |
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| Authors: | Luís SHP Vale Maria GPMS Neves Augusto C Tomé Filipe AA Paz |
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| Institution: | a Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal
b Department of Chemistry, CICECO, University of Aveiro, 3810-193 Aveiro, Portugal |
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| Abstract: | Gallium(III)(pyridine) complex of 5,10,15-tris(pentafluorophenyl)corrole-3-carbaldehyde was used as a precursor of an azomethine ylide, which was trapped in 1,3-dipolar cycloaddition reactions with quinones. Besides the expected dehydrogenated 1,3-dipolar cycloadducts, novel quinone-fused corrole derivatives were also obtained in moderate yields. |
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| Keywords: | Corroles 1 3-Dipolar cycloadditions Azomethine ylides Quinones |
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