Tunable Diode Laser Absorption Studies of Hydrocarbons in RF Plasmas Containing Hexamethyldisiloxane |
| |
Authors: | Röpcke J. Revalde G. Osiac M. Li K. Meichsner J. |
| |
Affiliation: | (1) Institute of Low Temperature Plasma Physics, F.-Ludwig-Jahn-Str. 19, D-17489 Greifswald, Germany;(2) Institute of Atomic Physics and Spectroscopy, University of Latvia, Raina 19, Riga, Latvia;(3) Institute of Physics, University of Greifswald, Domstr. 10a, D-17489 Griefswald, Germany |
| |
Abstract: | Tunable infrared diode laser absorption spectroscopy has been used to detect the methyl radical and three stable molecules, CH4, C2H2 and C2H6, in radio frequency plasmas (f=13.56 MHz) containing hexamethyldisiloxane (HMDSO). The methyl radical concentration and the concentration of the stable hydrocarbons, produced in the plasma, have been measured in pure HMDSO discharges and with admixtures of Ar, while discharge power (P=20–200 W), total gas pressure (p=0.08–0.6 mbar), gas mixture and total gas flow rate (=1–10 sccm) were varied. The methyl radical concentration was found to be in the range of 1013 molecules cm-3, while methane and ethane are the dominant hydrocarbons with concentrations of 1014–1015 mol cm-3. Conversion rates to the measured stable hydrocarbons (RC(CxHy): 2×1012–2×1016 molecules J-1 s-1) could be estimated in dependence on power, flow, mixture and pressure. Under the used experimental conditions a maximum deposition rate of polymer layers of about 400 nm min-1 has been found. |
| |
Keywords: | Radio frequency plasma plasma chemistry hexamethyldisiloxane laser diagnostics TDLAS CH3 CH4 C2H6 |
本文献已被 SpringerLink 等数据库收录! |
|