Catalysis Involving Multi-Centered Species on Nonuniform Surfaces, 2. Kinetics |
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| Authors: | Dmitry Yu. Murzin and Tapio Salmi |
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| Affiliation: | (1) Laboratory of Industrial Chemistry, Department of Chemical Engineering, Process Chemistry Group, Åbo Akademi, Biskopsgatan 8, FIN-20500 Åbo, Finland |
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| Abstract: | Multi-centered nature of adsorption as well as adsorbate-adsorbate interactions is addressed. A discussed reaction mechanism includes adsorption of a bulky molecule A, which requires several sites for adsorption, and two successive reaction steps of Eley type. Numerical treatment is performed for a special case of this mechanism. |
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| Keywords: | Kinetics non-uniform surfaces Eley mechanism |
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