Synthesis and spectroscopic study of the d-metal complexes with new octa(benzo-15-crown-5)-substituted phthalocyanine |
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| Authors: | N M Logacheva V E Baulin A Yu Tsivadze T V Basova L A Sheludyakova |
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| Institution: | (1) A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991 Moscow, Russian Federation;(2) Institute of Physiologically Active Compounds, Russian Academy of Sciences, 1 Severnyi proezd, 142432 Chernogolovka, Moscow Region, Russian Federation;(3) A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrent’eva, 630090 Novosibirsk, Russian Federation |
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| Abstract: | Octa(benzo-15-crown-5)-substituted phthalocyanine and its complexes with d-metals (NiII, CoII, CuII, ZnII, and CdII) have been synthesized for the first time. The compounds were studied by UV—Vis spectroscopy, MALDI-TOF mass spectrometry,
NMR, ESR, IR spectroscopy, and Raman spectroscopy. The dependence of the spectral characteristics of the studied compounds
on the ion radius of the complexing agent was demonstrated.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1439–1447, July, 2008. |
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| Keywords: | symmetric octasubstituted phthalocyanine crown ether d-metals metal complexes UV— Vis spectroscopy MALDI-TOF mass spectrometry NMR spectroscopy IR spectroscopy Raman spectroscopy electron spin resonance |
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