Ammoxidation of halogen-substituted toluenes on V-P-oxide catalysts |
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| Authors: | A Martin B Lücke H Seeboth G Ladwig and E Fischer |
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| Institution: | (1) Central Institute of Organic Chemistry, 1199 Berlin, GDR;(2) Central Institute of Inorganic Chemistry, 1199 Berlin, GDR;(3) Section of Chemistry, W.-Pieck-University, 2500 Rostock, GDR |
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| Abstract: | The ammoxidation of various halogen-substituted toluenes on crystalline vanadium phosphate catalysts was investigated. The monophosphates and the NH4VOP2O7 are transformed into new NH4-containing V-P-oxides. The (VO)2P2O7 used is stable in time on stream. These structures are very active and selective ammoxidation catalysts.
                        .  NH4VOP2O7 V-P ,  NH4. (VO)2P2O7  .    .
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