Benzotriazole-assisted thioacylation |
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Authors: | Katritzky Alan R Witek Rachel M Rodriguez-Garcia Valerie Mohapatra Prabhu P Rogers James W Cusido Janet Abdel-Fattah Ashraf A A Steel Peter J |
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Institution: | Center for Heterocyclic Compounds, Department of Chemistry, University of Florida, Gainesville, Florida 32611-7200, USA. Katritzky@chem.ufl.edu |
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Abstract: | Chemical reaction: See text] Benzotriazole reagents for thioacylation (RCSBt), thiocarbamoylation (RR'NCSBt), aryl/alkoxythioacylation (ROCSBt), and aryl/alkylthiothioacylation (RSCSBt) are synthesized, and their utility is assessed by syntheses of representative heteroaryl thioureas 3a-g, thioamides 15a-s, thionoesters 16a-h, thiocarbamates 17a-e, dithiocarbamates 18a-d, thiocarbonates 19a-c, and dithiocarbonates 20a-c. |
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