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Benzotriazole-assisted thioacylation
Authors:Katritzky Alan R  Witek Rachel M  Rodriguez-Garcia Valerie  Mohapatra Prabhu P  Rogers James W  Cusido Janet  Abdel-Fattah Ashraf A A  Steel Peter J
Institution:Center for Heterocyclic Compounds, Department of Chemistry, University of Florida, Gainesville, Florida 32611-7200, USA. Katritzky@chem.ufl.edu
Abstract:Chemical reaction: See text] Benzotriazole reagents for thioacylation (RCSBt), thiocarbamoylation (RR'NCSBt), aryl/alkoxythioacylation (ROCSBt), and aryl/alkylthiothioacylation (RSCSBt) are synthesized, and their utility is assessed by syntheses of representative heteroaryl thioureas 3a-g, thioamides 15a-s, thionoesters 16a-h, thiocarbamates 17a-e, dithiocarbamates 18a-d, thiocarbonates 19a-c, and dithiocarbonates 20a-c.
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