Hybrid porous tin(IV) phosphonate: an efficient catalyst for adipic acid synthesis and a very good adsorbent for CO2 uptake |
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| Authors: | Dutta Arghya Pramanik Malay Patra Astam K Nandi Mahasweta Uyama Hiroshi Bhaumik Asim |
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| Affiliation: | Department of Materials Science, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700 032, India. |
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| Abstract: | A new porous organic-inorganic hybrid tin phosphonate material has been synthesized hydrothermally, which shows a Brunauer-Emmett-Teller surface area of 723 m(2) g(-1) and it adsorbs 4.8 mmol g(-1) CO(2) at 273 K and 5 bar pressure. The material also shows remarkable catalytic activity in one-pot liquid phase oxidation of cyclohexanone to adipic acid under eco-friendly conditions. |
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