| 液/液两相催化高碳烯烃氢甲酰化反应 |
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| 引用本文： | 冯翠兰,王艳华,金子林.液/液两相催化高碳烯烃氢甲酰化反应[J].化学进展,2005,17(2):209-216. |
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| 作者姓名： | 冯翠兰 王艳华 金子林 |
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| 作者单位： | 大连理工大学,精细化工国家重点实验室,大连,116012;大连理工大学,精细化工国家重点实验室,大连,116012;大连理工大学,精细化工国家重点实验室,大连,116012 |
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| 基金项目： | 国家自然科学基金 (No .2 0 376 0 13,2 990 6 0 0 1,2 9876 0 0 4 )，教育部博士点科研基金 (No .2 0 0 2 0 14 10 0 4 )资助 |
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| 摘 要： | 结合作者近年来的研究工作 ,对液/ 液两相催化高碳烯烃氢甲酰化的研究进展作一综述 ,针对经典的水/有机两相体系不能用于高碳烯烃氢甲酰化的问题 ,全面介绍了适用于高碳烯烃水/有机两相氢甲酰化的温控相转移催化等 6种改进方法。同时 ,对 90年代以来发展迅速的氟两相、离子液体两相、超临界流体等非水液/液两相体系中的高碳烯烃氢甲酰化作了系统阐述 ,对它们的应用前景进行了评较。
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| 关 键 词： | 氢甲酰化反应 水/有机两相 温控相转移催化 氟两相 离子液体两相 超临界流体 温控相分离催化 |
| 文章编号： | 1005-281X(2005)02-0209-08 |
| 修稿时间： | 2003年12月1日 |
The Development in Hydroformylation of Higher Olefin in Liquid/ Liquid Biphase Systems |
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| Feng Cuilan,Wang Yanhua,Jin Zilin.The Development in Hydroformylation of Higher Olefin in Liquid/ Liquid Biphase Systems[J].Progress in Chemistry,2005,17(2):209-216. |
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| Authors: | Feng Cuilan Wang Yanhua Jin Zilin |
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| Institution: | Feng Cuilan Wang Yanhua Jin Zilin ** |
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| Abstract: | The development in hydroformylation of higher olefins in liquid/liquid biphase systems is reviewed, partially based on the authors' research results in recent years. The classical aqueous/organic biphase system is unsuitable for hydroformylation of higher olefins. In order to solve this problem, six kinds of improved methods including thermoregulated phase-transfer catalysis are introduced in detail. In addition, the hydroformylation of higher olefins in nonaqueous liquid/liquid biphase systems, such as fluorous biphasic system, non-aqueous ionic liquid and supercritical fluid is also introduced. Meanwhile, the possibilities of commercial applications of each system have been discussed. |
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| Keywords: | hydroformylation aqueoues/organic biphase system thermoregulated phase-transfer catalysis fluorous biphasic system non-aqueous ionic liquid supercritical fluid thermoregulated phase-separable catalysis |
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