Synthesis of a new stable conformationally constrained 2,7-anhydrosialic acid derivative |
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| Authors: | Liu Ke-Gang Zhou Hai-Bin Wu Yu-Lin Yao Zhu-Jun |
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| Affiliation: | State Key Laboratory of Bioorganic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenlin Road, Shanghai 200032, China. |
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| Abstract: | A stereoseletive synthesis of 2,7-anhydrosialic acid derivative 18 was achieved from d-glucono-delta-lactone. A highly syn-selective addition of Grignard reagent to theN-benzylimine 8 served as a key step. |
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