| 钴镍取代杂多酸盐甘氨酸超分子化合物的合成及性质 |
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| 引用本文： | 马荣华,王福平. 钴镍取代杂多酸盐甘氨酸超分子化合物的合成及性质[J]. 无机化学学报, 2006, 22(6): 1137-1142 |
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| 作者姓名： | 马荣华 王福平 |
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| 作者单位： | 1. 哈尔滨工业大学应用化学系,哈尔滨,150080;齐齐哈尔大学化学化工学院,齐齐哈尔,161006
2. 哈尔滨工业大学应用化学系,哈尔滨,150080 |
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| 基金项目： | 黑龙江省教育厅科学技术研究项目;黑龙江省教育厅骨干教师基金 |
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| 摘 要： | Supermolecular compounds of glycine monosubstituted heteropolytungstates isomer with Keggin structure βi-K6-n(HGly)n[SiW11M(H2O)O39]·xH2O (M=Co2+, Ni2+； βi=β2, β3) were synthesized and characterized by means of elementary analysis, IR, UV, TG-DTA, X-ray diffraction, polarography and CV. The results indicate that glycin combines the electrostatic effect with heteropolytungstates isomer. The heteropoly anion still remains its Keggin structure in supermolecular compounds. The electrochemical behavior of the compound in 1 mol·L-1 HAc-NaAc shows that two redox waves correspond to two two-electron processes attributing to the reduction of [SiW11Co(H2O)O39]6-. Steady-state fluorescence spectrum shows two intenser fluorescence emission peaks in 447 nm and 486 nm appeared after the supermolecular compound being excited by the excitation wavelength in 274 nm.
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| 关 键 词： | 杂多钨酸盐； 甘氨酸； 超分子 |
| 文章编号： | 1001-4861(2006)06-1137-06 |
| 收稿时间： | 2006-02-24 |
| 修稿时间： | 2006-04-19 |
Synthesis and Properties of Supermolecular Compounds of Glycine Cobalt(Nickel) Substituted Heteropolytungstates |
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| MA Rong-Hua and WANG Fu-Ping. Synthesis and Properties of Supermolecular Compounds of Glycine Cobalt(Nickel) Substituted Heteropolytungstates[J]. Chinese Journal of Inorganic Chemistry, 2006, 22(6): 1137-1142 |
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| Authors: | MA Rong-Hua and WANG Fu-Ping |
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| Affiliation: | Department of Applied Chemistry, Harbin Institute of Technology, Harbin 150080;College of Chemistry and Engineering, Qiqihar University, Qiqihar, Heilongjiang 161006 and Department of Applied Chemistry, Harbin Institute of Technology, Harbin 150080 |
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| Abstract: | |
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| Keywords: | heteropolytungstates glycine supermolecule |
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